Thermodynamics- Bomb Calorimeter and heat of combustion

Started by ann, February 08, 2023, 11:29:42 PM

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ann

 I need some help with these questions
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uma

In bomb calorimeter
q(water ) = C Delta t  = Heat of combustion of 1.535 g CH3OH
q(water) in  kJ .

∆H = - q (water)/ n
n = moles of methanol.

uma

Quote from: ann on February 08, 2023, 11:29:42 PM
I need some help with these questions
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Enthalpy of formation reaction is
C(s) +2S (s) ---> CS2---∆Hreaction
Use Hess's law
CS2 + 3O2------> CO2   + 2SO2--- ∆H1
S(s)    + O2 ---> SO2---∆H2
C(s)    + O2 ---> CO2---∆H3
∆Hreaction = -∆H1 +2∆H2 +∆H3




uma

Quote from: ann on February 08, 2023, 11:29:42 PM
I need some help with these questions
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This is based on law of conservation of energy.
Heat lost by one system of water at high temperature = heat gained by another system of water(low temperature)
Final temperature of both the systems will be same as they get the thermal equilibrium.Let us assume final temperature is x.
q(lost) =- mc ∆ t = - 100 * 4.18*(x-80)
q(gained) = m ∆H fusion of ice  + mc∆t = 10*335 + 10 4.18(x-0)
Equate these equations to get the value of x .

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