Steady State Equilibrium 5.9 Quiz

Started by Anil, December 30, 2023, 12:05:35 PM

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Anil

In this question, I couldn't reconcile with the answer.

1. Step 3 is slowest
2. So rate law = k [NO+] [ NH3]
3. But we cannot have a rate law in terms of intermediates
4. NH3 is intermediate. So per rate law of step 2, R = k[NH4+]
5. So overall rate law is R = k[NO+] [NH4+]

Please explain the logic of your answer and where am I wrong

uma

Overall reaction is
HNO2 + NH4+ ...> 2H2O +N2

Rate law for step I
Rate = k[HNO2][H+]
Rate law for step 2
Rate = k[NH4+]
step 3
Rate =k[NO+][NH3]

This step is rate law determining step and you need to remove intermediate by  reactants from which these intermediates are formed.
Replace NO+ by HNO2 and H+
Replace NH3 by NH4+
Here H+  is the catalyst.

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