ChemTopper Free Chemistry Help

Chemistry Homework Help => AP Chemistry => Topic started by: Montana Duke on November 05, 2015, 02:07:13 PM

Title: Re: Thermodynamics
Post by: Montana Duke on November 05, 2015, 02:07:13 PM
I have another question. 2 C4H10(g) + 13 O2(g) -> 8 CO2(g) + 10 H2O(g)

a) Find the standard enthalpy change, Delta{H}^{o}, for the reaction above using the information given in the following table.
                                                              Standard Enthalpy Change, Delta{H}^{o}
                                                                          (kJ mol raised to -1)
4 C(graphite) + 5 H2(g) -> C4H10(g)                     -123.73
C(graphite) + O2(g) -> CO2(g)                              -393.50
2 H2(g) + O2(g) -> 2 H2O(g)                                 -483.64

Title: Re: Thermodynamics
Post by: uma on November 05, 2015, 08:50:28 PM
Use Hess's law to solve this question
You need to  do changes in the equations  to get the desired equation
2 C4H10(g) + 13 O2(g) -> 8 CO2(g) + 10 H2O(g)....(DESIRED EQUATION)
4 C(graphite) + 5 H2(g) -> C4H10(g)  ----1                   -123.73
C(graphite) + O2(g) -> CO2(g)  ----2                            -393.50
2 H2(g) + O2(g) -> 2 H2O(g)     -----3                            -483.64
Just see how can you get 2 C4H10(g) on the left side ...reverse equation 1 and multiply it by 2 ,8CO2 on the right side ....multiply equation 2 by 6 , 10H2O(g) on the right side ...multiply equation 3 by 5 .Do the same changes on the enthalpies values of each equation.Remember if you reverse a chemical reaction then its enthalpies sign will also get reversed.
2C4H10(g) ---->8 C(graphite) + 10 H2(g)       2*123.73
8C(graphite) + 8O2(g) -> 8CO2(g)                     8* -393.50
10 H2(g) +5 O2(g) -> 10 H2O(g)                           5*-483.64
Now add all these changed equations and see if you are getting the desired reactions.Add all enthalpies values to get the enthalpy of the desired reaction.
Title: Re: Thermodynamics
Post by: Montana Duke on November 05, 2015, 08:58:48 PM
Thank you! That helps so much!  :D